| 1 | Alejandro Valverde (Spa) Movistar Team | 18:47:45 | |
| 2 | Richie Porte (Aus) Team Sky | 0:00:31 | |
| 3 | Luis León Sánchez (Spa) Caja Rural - Seguros RGA | 0:00:33 | |
| 4 | Jon Izagirre (Spa) Movistar Team | | |
| 5 | Tanel Kangert (Est) Astana Pro Team | 0:00:43 | |
| 6 | Bauke Mollema (Ned) Belkin-Pro Cycling Team | 0:00:55 | |
| 7 | Thomas Degand (Bel) Wanty - Groupe Gobert | 0:01:02 | |
| 8 | Daniel Navarro (Spa) Cofidis, Solutions Credits | 0:01:06 | |
| 9 | Michele Scarponi (Ita) Astana Pro Team | 0:01:13 | |
| 10 | Luis Angel Mate (Spa) Cofidis, Solutions Credits | 0:01:24 | |
| 11 | Geraint Thomas (GBr) Team Sky | 0:01:30 | |
| 12 | Marcos García (Spa) Caja Rural - Seguros RGA | 0:01:38 | |
| 13 | Sergio Pardilla Bellón (Spa) MTN - Qhubeka | 0:01:47 | |
| 14 | Haimar Zubeldia (Spa) Trek Factory Racing | 0:02:15 | |
| 15 | Bart De Clercq (Bel) Lotto Belisol | 0:02:17 | |
| 16 | Bert-Jan Lindeman (Ned) Rabobank Development Team | | |
| 17 | Francis De Greef (Bel) Wanty - Groupe Gobert | 0:02:21 | |
| 18 | Davide Rebellin (Ita) CCC Polsat Polkowice | | |
| 19 | Julien Simon (Fra) Cofidis, Solutions Credits | 0:02:28 | |
| 20 | Paolo Tiralongo (Ita) Astana Pro Team | 0:02:31 | |
| 21 | David Arroyo (Spa) Caja Rural - Seguros RGA | 0:02:40 | |
| 22 | Maxime Monfort (Bel) Lotto Belisol | 0:02:47 | |
| 23 | Amets Txurruka (Spa) Caja Rural - Seguros RGA | 0:03:01 | |
| 24 | Miguel Minguez (Spa) Euskadi | 0:03:05 | |
| 25 | Eliot Lietaer (Bel) Topsport Vlaanderen - Baloise | 0:03:30 | |
| 26 | Lars Petter Nordhaug (Nor) Belkin-Pro Cycling Team | 0:04:28 | |
| 27 | Laurens Ten Dam (Ned) Belkin-Pro Cycling Team | 0:05:26 | |
| 28 | Javier Megias Leal (Spa) Team Novo Nordisk | 0:05:28 | |
| 29 | Julian Arredondo (Col) Trek Factory Racing | 0:05:29 | |
| 30 | Antonio Piedra (Spa) Caja Rural - Seguros RGA | 0:06:38 | |
| 31 | Vasili Kiryienka (Blr) Team Sky | | |
| 32 | Tomasz Marczynski (Pol) CCC Polsat Polkowice | 0:07:11 | |
| 33 | Kristof Vandewalle (Bel) Trek Factory Racing | | |
| 34 | Maciej Paterski (Pol) CCC Polsat Polkowice | 0:07:29 | |
| 35 | Fredrik Kessiakoff (Swe) Astana Pro Team | 0:07:48 | |
| 36 | Lukasz Wisniowski (Pol) ETIXX | 0:08:05 | |
| 37 | José Herrada (Spa) Movistar Team | 0:08:45 | |
| 38 | Lukasz Owsian (Pol) CCC Polsat Polkowice | 0:08:55 | |
| 39 | Tom Dumoulin (Ned) Team Giant Shimano | 0:09:04 | |
| 40 | Edvald Boasson Hagen (Nor) Team Sky | 0:09:37 | |
| 41 | Edward Theuns (Bel) Topsport Vlaanderen - Baloise | 0:09:50 | |
| 42 | Tim Declercq (Bel) Topsport Vlaanderen - Baloise | 0:10:24 | |
| 43 | Bayron Guama De La Cruz (Ecu) Team Ecuador | 0:10:25 | |
| 44 | Rubén Plaza (Spa) Movistar Team | 0:10:34 | |
| 45 | Adrian Honkisz (Pol) CCC Polsat Polkowice | 0:10:50 | |
| 46 | Jakob Fuglsang (Den) Astana Pro Team | 0:10:51 | |
| 47 | Tom Van Asbroeck (Bel) Topsport Vlaanderen - Baloise | 0:11:28 | |
| 48 | Daniel Teklehaimanot (Eri) MTN - Qhubeka | 0:11:48 | |
| 49 | Jelle Vanendert (Bel) Lotto Belisol | 0:12:05 | |
| 50 | Markel Irizar (Spa) Trek Factory Racing | 0:12:15 |
